Special relativity can warp chemical bonds – now we’ve seen it happen
In some heavy atoms, like those of bismuth (pictured in crystalline form), electrons move at relativistic speeds savva_25/Shutterstock Albert Einstein’s theory of special relativity can reshape chemical bonds within molecules, and researchers have just seen it happen for the first time. The theory of special relativity describes how moving at speeds close to the speed of light would affect travellers’ experience of space and time. Because of this, it is usually associated with particle accelerators and spacefaring objects, but within some heavy atoms, electrons experience relativistic speeds too. Lai-Sheng Wang at Brown University in Rhode Island and his colleagues have now managed to take an unprecedented look at how this breaks the standard notion of chemical bonds within a charged molecule made from bismuth and carbon. Within the molecule, a bismuth atom and a carbon atom were connected by three bonds, one of which the researchers expected to be of “sigma” type and two of “pi” type. The difference between these two types stems from electrons’ quantum character – each electron is “smeared” across some …








